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LA GRAMMATICA DI ENGLISH GRATIS IN VERSIONE MOBILE   INFORMATIVA PRIVACY

  NUOVA SEZIONE ELINGUE

 

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WIKIBOOKS
DISPONIBILI
?????????

ART
- Great Painters
BUSINESS&LAW
- Accounting
- Fundamentals of Law
- Marketing
- Shorthand
CARS
- Concept Cars
GAMES&SPORT
- Videogames
- The World of Sports

COMPUTER TECHNOLOGY
- Blogs
- Free Software
- Google
- My Computer

- PHP Language and Applications
- Wikipedia
- Windows Vista

EDUCATION
- Education
LITERATURE
- Masterpieces of English Literature
LINGUISTICS
- American English

- English Dictionaries
- The English Language

MEDICINE
- Medical Emergencies
- The Theory of Memory
MUSIC&DANCE
- The Beatles
- Dances
- Microphones
- Musical Notation
- Music Instruments
SCIENCE
- Batteries
- Nanotechnology
LIFESTYLE
- Cosmetics
- Diets
- Vegetarianism and Veganism
TRADITIONS
- Christmas Traditions
NATURE
- Animals

- Fruits And Vegetables



ARTICLES IN THE BOOK

  1. AAAA battery
  2. AAA battery
  3. AA battery
  4. A battery
  5. Absorbent glass mat
  6. Alessandro Volta
  7. Alkaline battery
  8. Alkaline fuel cell
  9. Aluminium battery
  10. Ampere
  11. Atomic battery
  12. Backup battery
  13. Baghdad Battery
  14. Batteries
  15. Battery charger
  16. B battery
  17. Bernard S. Baker
  18. Beta-alumina solid electrolyte
  19. Betavoltaics
  20. Bio-nano generator
  21. Blue energy
  22. Bunsen cell
  23. Car battery
  24. C battery
  25. Clark cell
  26. Concentration cell
  27. Coulomb
  28. 2CR5
  29. Daniell cell
  30. Direct borohydride fuel cell
  31. Direct-ethanol fuel cell
  32. Direct methanol fuel cell
  33. Dry cell
  34. Dry pile
  35. Duracell
  36. Duracell Bunny
  37. Earth battery
  38. Electric charge
  39. Electric current
  40. Electricity
  41. Electrochemical cell
  42. Electrochemical potential
  43. Electro-galvanic fuel cell
  44. Electrolysis
  45. Electrolyte
  46. Electrolytic cell
  47. Electromagnetism
  48. Electromotive force
  49. Energizer Bunny
  50. Energy
  51. Energy density
  52. Energy storage
  53. Flashlight
  54. Float charging
  55. Flow Battery
  56. Formic acid fuel cell
  57. Fuel cell
  58. Fuel cell bus trial
  59. Galvanic cell
  60. Gel battery
  61. Grove cell
  62. Half cell
  63. History of the battery
  64. Hybrid vehicle
  65. Lead-acid battery
  66. Leclanché cell
  67. Lemon battery
  68. List of battery sizes
  69. List of battery types
  70. List of fuel cell vehicles
  71. Lithium battery
  72. Lithium ion batteries
  73. Lithium iron phosphate battery
  74. Lithium polymer cell
  75. LR44 battery
  76. Luigi Galvani
  77. Manganese dioxide
  78. Memory effect
  79. Mercury battery
  80. Metal hydride fuel cell
  81. Methane reformer
  82. Methanol reformer
  83. Michael Faraday
  84. Microbial fuel cell
  85. Molten carbonate fuel cell
  86. Molten salt battery
  87. Nickel-cadmium battery
  88. Nickel-iron battery
  89. Nickel metal hydride
  90. Nickel-zinc battery
  91. Open-circuit voltage
  92. Optoelectric nuclear battery
  93. Organic radical battery
  94. Oxyride battery
  95. Panasonic EV Energy Co
  96. Peukert's law
  97. Phosphoric acid fuel cell
  98. Photoelectrochemical cell
  99. Polymer-based battery
  100. Power density
  101. Power management
  102. Power outage
  103. PP3 battery
  104. Primary cell
  105. Prius
  106. Proton exchange membrane
  107. Proton exchange membrane fuel cell
  108. Protonic ceramic fuel cell
  109. Radioisotope piezoelectric generator
  110. Ragone chart
  111. RCR-V3
  112. Rechargeable alkaline battery
  113. Reverse charging
  114. Reversible fuel cell
  115. Searchlight
  116. Secondary cell
  117. Short circuit
  118. Silver-oxide battery
  119. Smart Battery Data
  120. Smart battery system
  121. Sodium-sulfur battery
  122. Solid oxide fuel cell
  123. Super iron battery
  124. Thermionic converter
  125. Trickle charging
  126. Vanadium redox battery
  127. Volt
  128. Voltage
  129. Voltaic pile
  130. Watch battery
  131. Water-activated battery
  132. Weston cell
  133. Wet cell
  134. Zinc-air battery
  135. Zinc-bromine flow battery
  136. Zinc-carbon battery

 

 
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    ENGLISHGRATIS.COM è un sito personale di
    Roberto Casiraghi e Crystal Jones
    email: robertocasiraghi at iol punto it

    Roberto Casiraghi           
    INFORMATIVA SULLA PRIVACY              Crystal Jones


    Siti amici:  Lonweb Daisy Stories English4Life Scuolitalia
    Sito segnalato da INGLESE.IT

 
 



BATTERIES
This article is from:
http://en.wikipedia.org/wiki/Direct_methanol_fuel_cell

All text is available under the terms of the GNU Free Documentation License: http://en.wikipedia.org/wiki/Wikipedia:Text_of_the_GNU_Free_Documentation_License 

Direct methanol fuel cell

From Wikipedia, the free encyclopedia

 

Direct-methanol fuel cells or DMFCs are a subcategory of proton-exchange fuel cells where, the fuel, methanol (CH3OH), is not reformed, but fed directly to the fuel cell. Because methanol is fed directly into the fuel cell, complicated catalytic reforming is unneeded, and storage of methanol is much easier than that of hydrogen because it does not need to be done at high pressures or low temperatures, as methanol is a liquid from -97.0 °C to 64.7 °C (-142.6 °F to 148.5 °F). The energy density of methanol, the amount of energy released by using a given volume of methanol, is orders of magnitude greater than even highly compressed hydrogen.

However, the efficiency of direct-methanol fuel cells is low due to the high permeation of methanol through the membrane, which is known as methanol crossover, and the dynamic behaviour is sluggish. Other problems include the management of carbon dioxide evolved at the anode. At the current level of the technology, DMFCs are limited in the power they can produce, but can still store much energy in a small space. This means they can produce a small amount of power over a long period of time. This makes them ill-suited for powering vehicles, but ideal for consumer goods such as mobile phones, digital cameras or laptops.

Another issue is methanol's chemical properties. It is toxic and flammable. However, the International Civil Aviation Organization's (ICAO) Dangerous Goods Panel (DGP) voted in November 2005 to allow passengers to carry and use micro fuel cells and methanol fuel cartridges when aboard airplanes to power laptop computers and other consumer electronic devices. The formal regulation is still waiting to be implemented.

Reaction

The DMFC relies upon the oxidation of methanol on a catalyst layer to form carbon dioxide. Water is consumed at the anode and is produced at the cathode. Positive ions (H+) are transported across the proton exchange membrane (often Nafion) to the cathode where they react with oxygen to produce water. Electrons are transported via an external circuit from anode to cathode providing power to external devices.

The half-reactions are:

Anode: CH3OH + H2O → CO2 + 6H+ + 6e-

Cathode: (3/2)O2 + 6H+ + 6e- → 3H2O

Net reaction: CH3OH + 1.5O2 → CO2 + 2H2O

Because water is consumed at the anode in the reaction, pure methanol cannot be used without provision of water via either passive transport such as back diffusion (osmosis), or active transport such as pumping. The need for water limits the energy density of the fuel.

Currently, platinum is used as a catalyst for both half-reactions. This is what causes the problem of methanol crossover, as any methanol that is present in the cathode chamber will oxidize. If another catalyst could be found for the reduction of oxygen, the problem of methanol crossover would likely be significantly lessened. Also, platinum is very expensive, which inhibits commercial production of the DMFC.

History

(Inverse timeline)

December 29, 2006. Samsung recently announced new breakthrough in this tech. Expect commercial sales of laptop batteries by end of 2007 (i.e. in Q35 laptop). [1]

As of 2005, the record for the smallest commercially available fuel cell is held by Toshiba, at 22 x 56 x 4.5 millimeters. This device outputs 100 milliwatts at 10 hours per milliliter of fuel, and takes advantage of new technology allowing the use of undiluted (99.5%) methanol.

 


 

See also

  • Liquid fuels
  • Methanol (data page)
  • Methanol economy

External links

  • World's Smallest DMFC
  • Standards for Transportable Fuel Cell Power Units
Retrieved from "http://en.wikipedia.org/wiki/Direct_methanol_fuel_cell"