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This article has been tagged since October 2006.
The Clark cell, invented by English engineer
Josiah Latimer Clark in
1873,
is a
wet-chemical cell (colloquially: battery) that
produces a highly stable voltage usable as a laboratory
standard.
Clark cells use a zinc amalgam anode and a mercury cathode in
a saturated aqueous zinc sulphate electrolyte, yielding a
reference
EMF of 1.4328
Volts.
(Reference cells must be applied in such a way that no current
is drawn from them.)
The design had two drawbacks - a rather large temperature
coefficient of -1.15 mV/°C, and corrosion problems caused by the
platinum electrodes alloying with the zinc amalgam connections
where they enter the glass envelope.
Clark cells were later made obsolete by the more
temperature-independent
Weston cell design.
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