From Wikipedia, the free encyclopedia
Castor oil is a
vegetable oil obtained from the
castor bean (technically castor seed as the castor
plant, Ricinus communis, is not a member of the
bean
family).
Castor oil has an unusual composition and chemistry, which
makes it quite valuable. Ninety percent of fatty acids in castor
oil are
ricinoleic acid. Ricinoleic acid, a
monounsaturated, 18-carbon
fatty acid, has a
hydroxyl
functional group at the twelfth carbon, a very uncommon
property for a biological fatty acid. This functional group
causes ricinoleic acid (and castor oil) to be unusually
polar, and also allows chemical derivatization that is not
practical with other biological oils. Since it is a polar
dielectric with a relatively high
dielectric constant (4.7), highly refined and dried Castor
oil is sometimes used as a dielectric fluid within high
performance high voltage
capacitors. Castor oil also contains 3-4% of both
oleic and
linoleic acids.[1]
Castor oil maintains its fluidity at both extremely high and
low temperatures.
Sebacic acid is chemically derived from castor oil. Castor
oil and its derivatives have applications in the manufacturing
of
soaps,
lubricants, hydraulic and
brake fluids,
paints,
dyes,
coatings,
inks,
cold resistant
plastics,
waxes
and polishes,
nylon,
pharmaceuticals and
perfumes. In
internal combustion engines, castor oil is renowned for its
ability to lubricate under extreme conditions and temperatures,
such as in
air-cooled engines. The lubricants company
Castrol takes its name from castor oil. However, castor oil
tends to form gums in a short time, and its use is therefore
restricted to engines that are regularly rebuilt, such as
motorcycle race engines.
Castor oil is vegetable-based oil because it's made
from
Castor plant seeds; thus, it naturally biodegrades quickly
and comes from a renewable energy resource (plants). The castor
seed contains
Ricin,
a toxic protein removed by cold pressing and filtering.
[2].
|
Contents
-
1
Castor oil fatty acids
-
2
Castor oil in food
-
3
Medicinal use of Castor oil
-
4
Traditional or folk medicines
-
5
Industrial Castor oil
-
6
Lamp fuel
-
7
Castor oil as a tool of
political terror
-
8
References
-
9
See also
|
Castor oil fatty acids
| Average composition of Castor seed oil /
fatty acids |
| Common Name |
Acid Name |
Average Percentage Range |
| Ricinoleate |
Ricinoleic acid |
85 |
to |
95% |
|
Oleate |
Oleic acid |
6 |
to |
2% |
|
Linoleate |
Linoleic acid |
5 |
to |
1% |
| Linolenate |
Linolenic acid |
1 |
to |
0.5% |
|
Stearate |
Stearic acid |
1 |
to |
0.5% |
|
Palmitate |
Palmitic acid |
1 |
to |
0.5% |
| Dihydroxystearate |
Dihydroxystearic acid |
0.5 |
to |
0.3% |
| Trace amounts (other) |
fatty acids |
0.5 |
to |
0.2% |
Castor oil in food
In the food industry, Castor oil (food grade) is used in food
additives
[2], flavorings, candy (i.e., chocolate)
[3],
as a mold inhibitor, and in packaging. Polyoxyethylated Castor
oil (a.k.a. Cremophor)
[4] is also used in the
foodstuff industries
[5].
Medicinal use of Castor oil
Today, the United States Food and Drug Administration (FDA)
recognizes Castor oil as generally safe and effective (GRASE)
for over-the-counter use as a laxative
[6],
but it is not a preferred drug to treat constipation.
[7]
Besides being a laxative, Castor oil is used throughout the
world to help women start labor.[3]
One of Castor oil's derivatives
undecylenic acid is also FDA approved for over-the-counter
use on skin disorders or skin problems.
[8].
Pure cold pressed Castor oil is really tasteless and
odorless. When additives are added to pure cold pressed Castor
oil, the oil becomes adulterated and the taste and smell can
change according to the additives. Also, pure cold pressed
Castor oil is potent and can be an eye irritant similar to
pepper spray, so avoid contact with eyes.
[4]
Ricinoleic acid is the main component of Castor oil and it
exerts anti-inflammatory effects
[9].
A study found that castor oil decreased pain more than
ultrasound gel or vaseline during extracorporeal shock wave
application
[10].
Therapeutically, modern drugs are rarely given in a pure
chemical state, so most active ingredients are combined with
excipients or additives. Castor oil in the form of
Cremophor EL (polyethoxylated Castor oil: a mixture of
ricinoleic acid, polyglycol ester, glycerol polyglycol esters,
and polyglycols) is added to many modern drugs such as:
Miconazole, anti-fungal
[11]
[12];
Paclitaxel, anti-cancer
[13]; Sandimmune (cyclosporine
injection, USP)
[14];
Nelfinavir mesylate,
HIV
protese inhibitor
[15]. Saperconazole has
Emulphor EL -719P (a castor oil derivative)
[16];
Prograf has HCO-60 (polyoxyl 60 hydrogenated Castor oil);
Balsam Peru - Castor oil - and Trypsin Topical contains
Castor oil
[17]; Aci-Jel (acetic
acid/oxyquinoline/ricinoleic
acid - vaginal); Emla (lidocaine,
prilocaine and Castor oil)
[18].
Traditional or folk medicines
Cold pressed Castor oil has been used or time-tested for
centuries throughout the world for its anti-microbial and
anti-bacterial properties long before any government agency was
created to regulate medicines.
Medicinal Castor oil was used for skin problems, burns,
sunburns, skin disorders, skin cuts, abrasions, etc.
The oil is also used as a rub or pack for various ailments,
including abdominal complaints, headaches, muscle pains,
inflammatory conditions, skin eruptions, lesions, and sinusitis.
A castor oil pack is made by soaking a piece of flannel in
castor oil, then putting it on the area of complaint and placing
a heat source, such as a hot water bottle, on top of it.
Industrial Castor oil
Castor oil has over 1000 patented industrial applications
[5] and is used in the following industries: automobile,
aviation, cosmetics, electrical, electronics, manufacturing,
pharmaceutical, plastics, and telecommunications. The following
is a brief list of Castor oil uses in the above industries:
adhesives, brake fluids, caulks, dyes, electrical liquid
dielectrics, humectants, hydraulic fluids, inks, lacquers,
leather treatments, lubricating greases, machining oils, paints,
pigments, refrigeration lubricants, rubbers, sealants, textiles,
washing powders, and waxes.
Castor oil's high lubricity (reduces friction) is
superior to petroleum-based lubricants; for instance, it really
clings to metal, especially hot metal, and is used in racing and
jet (turbine) engines. In addition, Castor oil is non-toxic and
quickly biodegrades; whereas, petroleum-based oils are potential
health hazards, and take a very long time to biodegrade, thus
can damage the environment when concentrated
[19].
Castor oil is non-drying oil (slow to oxidize); thus, it
remains liquid for a long time. As a result, it's naturally a
good lubricant, and was a fuel for lamps before alternating
current electricity (AC) was invented.
Castor oil's value was recognized by the United States
Congress in the Agricultural Materials Act of 1984, and
classified as a strategic material.
Lamp fuel
It is said to be the best lamp oil in use in India, giving an
excellent white light, vying in brilliancy with electricity, far
superior to petroleum, rape seed, and all other oils, whether
vegetable, animal or mineral.
[6]
In Bangladesh, some villagers use castor oil instead of
kerosene to fuel lamps.
Castor oil as a tool of political
terror
In
Fascist Italy under the regime of
Benito Mussolini, castor oil was one of the tools of the
blackshirts.
Political dissidents were force-fed large quantities of
castor oil by Fascist
paramilitary groups. This technique was said to have been
originated by
Gabriele D'Annunzio. Victims of this treatment would
experience severe
diarrhea and
dehydration, often resulting in death[7].
Sometimes when the blackshirts wished to make sure that the
victim would die rather than simply be badly disabled, they
would mix
gasoline with the castor oil.
It is said that Mussolini's power was backed by "the
bludgeon and castor oil."
References
- ^
Soap Making Oil Properties. Saratoga Scents. Retrieved
on
2006-10-09.
- ^
Castor Oil is non-toxic. ICOA. Retrieved on
2006-12-28.
- ^
Overview of the preperation, use and biological studies on
polyglycerol polyricinoleate (PGPR).. PubMed. Retrieved
on
2007-01-26.
- ^
Development and validation of HPLC methods for the
determination of potential extractables from elastomeric
stoppers in the presence of a complex surfactant vehicle
used in the preparation of parenteral drug products..
PubMed. Retrieved on
2007-01-26.
- ^
Cremophor EL stimulates mitotic recombination in uvsH//uvsH
diploid strain of Aspergillus nidulans.. PubMed.
Retrieved on
2007-01-26.
- ^
Ingredient List A-C. FDA (see page 52 of this link).
Retrieved on
2006-12-28.
- ^ Castor
Oil. DRUGDEX® System. n.d. Thomson Micromedex. Retrieved
February 19, 2007
[1]
- ^
Ingredient List P-Z. FDA (see page 65 of this link).
Retrieved on
2006-12-28.
- ^
Effect of ricinoleic acid in acute and subchronic
experimental models of inflammation. PubMed. Retrieved
on
2007-01-06.
- ^
Castor oil decreases pain during extracorporeal shock wave
application. PubMed. Retrieved on
2007-01-15.
- ^
Reversible Thrombocytosis and Anemia Due to Miconazole
Therapy (pdf). PubMed. Retrieved on
2007-01-06.
See page 1, Methods and Materials.
- ^
Overview of medically important antifungal azole derivatives
(pdf). PubMed. Retrieved on
2007-01-06.
See page 6, /192, Clinical studies
- ^
Abraxane in the treatment of ovarian cancer: the absence of
hypersensitivity reactions. PubMed. Retrieved on
2007-01-06.
- ^
Sandimmune ingredients. DailyMed. Retrieved on
2007-01-06.
- ^
Circulating metabolites of the Human Immunodeficiency Virus
Protese Inhibitor Nelfinavir in Humans:. PubMed.
Retrieved on
2007-01-06.
- ^
Saperconazole Therapy of Murine Disseminated Candidiasis:.
PubMed. Retrieved on
2007-01-06.
- ^
Heparin - induced thrombocytopenia syndrome bullous lesions
treated with trypsin - balsam of peru - castor oil ointment:
a case study.. PubMed. Retrieved on
2007-01-06.
- ^
Contact urticaria from Emla cream. PubMed. Retrieved on
2007-01-06.
- ^
Petroleum Oil and the Environment. DOE. Retrieved on
2006-12-28.
8 ^Castor Oil: Uses. Retreived 31 December 2006.
http://www.annieappleseedproject.org/castoroiluses.html
See also
Categories:
Laxatives |
Lubricants |
Vegetable oils |
Dielectrics |
Cosmetic chemicals