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ARTICLES IN THE BOOK

1. Atomic force microscope
2. Atomic nanoscope
3. Atom probe
4. Ballistic conduction
5. Bingel reaction
6. Biomimetic
7. Bio-nano generator
8. Bionanotechnology
9. Break junction
10. Brownian motor
11. Bulk micromachining
12. Cantilever
13. Carbon nanotube
14. Carbyne
15. CeNTech
16. Chemical Compound Microarray
17. Cluster
18. Colloid
19. Comb drive
20. Computronium
22. Diamondoids
23. Dielectrophoresis
24. Dip Pen Nanolithography
25. DNA machine
26. Ecophagy
27. Electrochemical scanning tunneling microscope
28. Electron beam lithography
29. Electrospinning
30. Engines of Creation
31. Exponential assembly
32. Femtotechnology
33. Fermi point
34. Fluctuation dissipation theorem
35. Fluorescence interference contrast microscopy
36. Fullerene
37. Fungimol
38. Gas cluster ion beam
39. Grey goo
40. Hacking Matter
41. History of nanotechnology
42. Hydrogen microsensor
43. Inorganic nanotube
44. Ion-beam sculpting
45. Kelvin probe force microscope
46. Lab-on-a-chip
47. Langmuir-Blodgett film
48. LifeChips
49. List of nanoengineering topics
50. List of nanotechnology applications
51. List of nanotechnology topics
52. Lotus effect
53. Magnetic force microscope
54. Magnetic resonance force microscopy
55. Mechanochemistry
56. Mechanosynthesis
57. MEMS thermal actuator
58. Mesotechnology
59. Micro Contact Printing
60. Microelectromechanical systems
61. Microfluidics
62. Micromachinery
63. Molecular assembler
64. Molecular engineering
65. Molecular logic gate
66. Molecular manufacturing
67. Molecular motors
68. Molecular recognition
69. Molecule
70. Nano-abacus
71. Nanoart
72. Nanobiotechnology
73. Nanocar
74. Nanochemistry
75. Nanocomputer
76. Nanocrystal
77. Nanocrystalline silicon
78. Nanocrystal solar cell
79. Nanoelectrochemistry
80. Nanoelectrode
81. Nanoelectromechanical systems
82. Nanoelectronics
83. Nano-emissive display
84. Nanoengineering
85. Nanoethics
86. Nanofactory
87. Nanoimprint lithography
88. Nanoionics
89. Nanolithography
90. Nanomanufacturing
91. Nanomaterial based catalyst
92. Nanomedicine
93. Nanomorph
94. Nanomotor
95. Nano-optics
96. Nanoparticle
97. Nanoparticle tracking analysis
98. Nanophotonics
99. Nanopore
100. Nanoprobe
101. Nanoring
102. Nanorobot
103. Nanorod
104. Nanoscale
105. Nano-Science Center
106. Nanosensor
107. Nanoshell
108. Nanosight
109. Nanosocialism
110. Nanostructure
111. Nanotechnology
112. Nanotechnology education
113. Nanotechnology in fiction
114. Nanotoxicity
115. Nanotube
116. Nanovid microscopy
117. Nanowire
118. National Nanotechnology Initiative
119. Neowater
120. Niemeyer-Dolan technique
121. Ormosil
122. Photolithography
123. Picotechnology
124. Programmable matter
125. Quantum dot
126. Quantum heterostructure
127. Quantum point contact
128. Quantum solvent
129. Quantum well
130. Quantum wire
131. Richard Feynman
132. Royal Society's nanotech report
133. Scanning gate microscopy
134. Scanning probe lithography
135. Scanning probe microscopy
136. Scanning tunneling microscope
137. Scanning voltage microscopy
138. Self-assembled monolayer
139. Self-assembly
140. Self reconfigurable
141. Self-Reconfiguring Modular Robotics
142. Self-replication
143. Smart dust
144. Smart material
145. Soft lithography
146. Spent nuclear fuel
147. Spin polarized scanning tunneling microscopy
148. Stone Wales defect
149. Supramolecular assembly
150. Supramolecular chemistry
151. Supramolecular electronics
152. Surface micromachining
153. Surface plasmon resonance
154. Synthetic molecular motors
155. Synthetic setae
156. Tapping AFM
157. There's Plenty of Room at the Bottom
158. Transfersome
159. Utility fog

NANOTECHNOLOGY
http://en.wikipedia.org/wiki/Nanowire

All text is available under the terms of the GNU Free Documentation License: http://en.wikipedia.org/wiki/Wikipedia:Text_of_the_GNU_Free_Documentation_License

Nanowire

A nanowire is a wire of dimensions of the order of a nanometer (10−9 meters). Alternatively, nanowires can be defined as structures that have a lateral size constrained to tens of nanometers or less and an unconstrained longitudinal size. At these scales, quantum mechanical effects are important — hence such wires are also known as "quantum wires". Many different types of nanowires exist, including metallic (e.g., Ni, Pt, Au), semiconducting (e.g., InP, Si, GaN, etc.), and insulating (e.g., SiO2,TiO2). Molecular nanowires are composed of repeating molecular units either organic (e.g. DNA) or inorganic (e.g. Mo6S9-xIx).

The nanowires could be used, in the near future, to link tiny components into extremely smallcircuits. Using nanotechnology, such components could be created out of chemical compounds.

Overview

Typical nanowires exhibit aspect ratios (the ratio between length to width) of 1000 or more. As such they are often referred to as 1-Dimensional materials. Nanowires have many interesting properties that are not seen in bulk or 3-D materials. This is because electrons in nanowires are quantum confined laterally and thus occupy energy levels that are different from the traditional continuum of energy levels or bands found in bulk materials. Peculiar features of this quantum confinement exhibited by certain nanowires such as carbon nanotubes mainfest themselves in discrete values of the electrical conductance. Such discrete values arise from a quantum mechanical restraint on the number of electrons that can travel through the wire at the nanometer scale. These discrete values are often referred to as the quantum of conductance and are integer values of $\frac{2e^2}{h}$ ≈ 12.9 kΩ-1. They are inverse of the well-known resistance unit h/e², which is roughly equal to 25812.8 ohms, and referred to as the von Klitzing constant RK (after Klaus von Klitzing, the discoverer of exact quantization). Since 1990, a fixed conventional value RK-90 is accepted.

Examples of nanowires include inorganic molecular nanowires (Mo6S9-xIx), which have a diameter of 0.9 nm, and can be hundreds of micrometers long. Other important examples are based on semiconductors such as InP, Si, GaN, etc., dielectrics (e.g. SiO2,TiO2), or metals (e.g. Ni, Pt).

There are many applications where nanowires may become important in electronic, opto-electronic and nanoelectromechanical devices, as additives in advanced composites, for metallic interconnects in quantum devices, as field-emittors and as leads for biomolecular nanosensors.

Physics of nanowires

Production of nanowires

Nanowires are not observed spontaneously in nature and must be produced in a laboratory. Nanowires can be either suspended, deposited or synthesized from the elements.

A suspended nanowire is a wire in vacuum chamber held at the extremities. A deposited nanowire is a wire deposited on a surface of different nature: e.g. it could even be a single strip of metallic atoms over a non-conducting surface.

A suspended nanowire can be produced by chemical etching of a bigger wire, or bombarding a bigger wire with some highly energetic particles (atoms or molecules).

Another way to produce a suspended nanowire is to indent the tip of an STM in the surface, of a metal near the melting point, and retract it. This can form a wire very much like the tip of a fork does with the cheese of a pizza.

A common technique for creating a nanowire is the Vapor-Liquid-Solid (VLS) synthesis method. This technique uses as source material either laser ablated particles or a feed gas (such as silane). The source is then exposed to a catalyst. For nanowires, the best catalysts are liquid metal (such as gold) nanoclusters, which can either be purchased in colloidal form and deposited on a substrate or self-assembled from a thin film by dewetting. This process can often produce crystalline nanowires in the case of semiconductor materials.

The source enters these nanoclusters and begins to saturate it. Once supersaturation is reached, the source solidifies and grows outward from the nanocluster. The final product's length can be adjusted by simply turning off the source. Compound nanowires with super-lattices of alternating materials can be created by switching sources while still in the growth phase.

Conductivity of nanowires

The conductivity of a nanowire is expected to be much less than that of the corresponding bulk material. This is due to a variety of reasons. First, there is scattering from the wire boundaries, when the wire width is below the free electron mean free path of the bulk material. In copper, for example, the mean free path is 40 nm. Nanowires less than 40 nm wide will shorten the mean free path to the wire width.

Nanowires also show other peculiar electrical properties due to their size. Unlike carbon nanotubes, whose motion of electrons can fall under the regime of ballistic transport (meaning the electrons can travel freely from one electrode to the other), nanowire conductivity is strongly influenced by edge effects. The edge effects come from atoms that lay at the nanowire surface and are not fully bonded to neighboring atoms like the atoms within the bulk of the nanowire. The unbonded atoms are often a source of defects within the nanowire, and may cause the nanowire to conduct electricity more poorly than the bulk material. As a nanowire shrinks in size, the surface atoms becomes more numerous compared to the atoms within the nanowire, and edge effects become more important.

Furthermore the conductivity can undergo a quantization in energy: i.e. the energy of the electrons going through a nanowire can assume only discrete values, multiple of the Von Klitzing constant G = 2e2 / h (where e is the charge of the electron and h is Planck's constant).

The conductivity is hence described as the sum of the transport by separate channels of different quantized energy levels. The thinner the wire is, the smaller the number of channels available to the transport of electrons.

The conductivity of a nanowire can be studied suspending it between two electrodes. This has been proven by measuring the conductivity of a nanowire while pulling it: while it shrinks, its conductivity decreases in a stepwise fashion and the plateaus correspond to multiples of G.

The quantized conductivity is more pronounced in semiconductors like Si or GaAs than in metals, due to lower electron density and lower effective mass. Quantized conductance can be observed in 25 nm wide silicon fins (Tilke et. al., 2003), resulting in increased threshold voltage.

Structure of nanowires

The nanowires can show peculiar shapes. Sometimes they can show noncrystalline order, assuming e.g. a pentagonal symmetry or a helicoidal (spiral) shape. Electrons zigzag along pentagonal tubes and spiral along helicoidal tubes.

The lack of crystalline order is due to the fact that a nanowire is periodic only in one dimension (along its axis). Hence it can assume any order in the other directions (in plane) if this is energetically favorable.

E.g., in some cases nanowires can show a fivefold symmetry, usually not observed in nature, but for clusters of few atoms. The fivefold symmetry is equivalent to the icosahedral symmetry of (small) atomic clusters: the icosahedron is often an energetically favorable shape for cluster of few atoms, but icosahedral ordering is not observed in crystals since it is not possible to stack together icosahedra (repeating infinite copies of them in each direction) and tile the whole space (fill it without holes).

Use of nanowires

Nanowires still belong to the experimental world of laboratories. However, some early experiments have shown how they can be used to build the next generation of computing devices.

To create active electronic elements, the first key step was to chemically dope a semiconductor nanowire. This has already been done to individual nanowires to create p-type and n-type semiconductors.

The next step was to find a way to create a p-n junction, one of the simplest electronic devices. This was achieved in two ways. The first way was to physically cross a p-type wire over an n-type wire. The second method involved chemically doping a single wire with different dopants along the length. This method created a p-n junction with only one wire.

After p-n junctions were built with nanowires, the next logical step was to build logic gates. By connecting several p-n junctions together, researchers have been able to create the basis of all logic circuits: the AND, OR, and NOT gates have all been built from semiconductor nanowire crossings.

It's possible that semiconductor nanowire crossings will be important to the future of digital computing. Though there are other uses for nanowires beyond these, the only ones that actually take advantage of physics in the nanometer regime are electronic.

Nanotubes are being studied for use as photon ballistic waveguides as interconnects in quantum dot/quantum effect well photon logic arrays. Photons travel inside the tube, electrons travel on the outside shell.

When two nanotubes acting as photon waveguides cross each other the juncture acts as a quantum dot.

References

• K. v. Klitzing, G. Dorda, and M. Pepper; Phys. Rev. Lett. 45, 494-497 (1980)[1]
• R. Landauer, J. Phys.: Cond. Matter 1, 8099 (1989) [2]
• A. T. Tilke et. al., Physical Rev. B, vol. 68, 075311 (2003).